elvircrn 13 hours ago

---------------------------------------------------------------- Dear battery technology claimant,

Thank you for your submission of proposed new revolutionary battery technology. Your new technology claims to be superior to existing lithium-ion technology and is just around the corner from taking over the world. Unfortunately your technology will likely fail, because:

[ ] it is impractical to manufacture at scale.

[ ] it will be too expensive for users.

[ ] it suffers from too few recharge cycles.

[ ] it is incapable of delivering current at sufficient levels.

[ ] it lacks thermal stability at low or high temperatures.

[x] it lacks the energy density to make it sufficiently portable.

[ ] it has too short of a lifetime.

[ ] its charge rate is too slow.

[ ] its materials are too toxic.

[ ] it is too likely to catch fire or explode.

[ ] it is too minimal of a step forward for anybody to care.

[ ] this was already done 20 years ago and didn't work then.

[ ] by this time it ships li-ion advances will match it.

[ ] your claims are lies.

----------------------------------------------------------------

Source: https://news.ycombinator.com/item?id=26633670

  • hilbert42 43 minutes ago

    Right, all your points may be correct or are perhaps possible.

    Now would you kindly cite authoritative sources and references so we can verify your assertions.

  • joshu 10 hours ago

    there are uses for non-portable batteries

  • dyauspitr 13 hours ago

    What other boxes does it check because otherwise it’s viable for home scale uses.

    • senectus1 10 hours ago

      this is the stupid binary-ism that is holding us back. "its no good for X, so its immediately discounted for ANY solution".

      The issue plagues moving forward with other energy solutions like hydrogen.

      • Dylan16807 5 hours ago

        What's hydrogen a solution for?

        • chgs 2 hours ago

          Power supply to remote temporary areas like construction sites. Let’s say you need 100kW for 12 hours a day for a month to the middle of nowhere. You could run new power lines and get the connected, over land you don’t own, taking months. Or you could bring in a hydrogen generator and ship in new bottles to “recharge” it.

        • wqaatwt 3 hours ago

          More affordable blimps?

happosai 16 hours ago

Sulfur in mining tailings is huge problem ( https://en.wikipedia.org/wiki/Acid_mine_drainage ). This one reason there is so much research in Li-S batteries. Plenty of material innovations have come from people looking at mine tailings and wondering if something useful could me made of it.

  • rpaddock 16 hours ago

    For 22 years I designed the electronics controls that ran Longwall Coal Mining Machines. I've been in many mines.

    The problem with extracting things from tailings is that they are often contaminated with low levels of Thorium. Extracting the other things like Lithium, Sulfur etc, starts to build up the quantity of Thorium. Which sounds good if you want to build a molten salt Thorium reactor; I understand that China and India have prototype to come on line around 2027. Based on designs and experimental units that the US did in the ~1950s.

    The tailing problem is that the company is how handling Nuclear Grade Material which causes the Nuclear Regulatory Commission (NRC) to show up at the mine site. No mine wants to deal with this paper work, and health ramifications, headache so the tailings are not used.

    If the profit ratio to headaches would improve things might change.

    • mapt 14 hours ago

      This seems backwards.

      The tailings do not become nuclear waste when we decide to use them for something.

      • dcrazy 14 hours ago

        Perhaps the problem is that you are either refining away the thorium, or refining away as much non-thorium as you can. Either way you end up with mostly-thorium, and we know that radioactive stuff gets angry in large groups.

        • DennisP 13 hours ago

          Thorium does not get angry, because it's only slightly radioactive and it's not fissile. To start up a thorium reactor, you need enough plutonium or uranium spitting out neutrons to convert plenty of thorium to U233, which is what fissions and makes energy.

          If you want an actual bomb, you need that U233 without any thorium, because the thorium mostly just turns to U233 when it absorbs a thermal neutron (i.e. slowed down by a moderator like graphite). In a bomb you're relying on fast neutrons.

          Read enough books/articles on thorium reactors and you'll come across a photo of the US thorium stockpile, which is a great big stack of pure thorium bricks.

      • westmeal 14 hours ago

        Everythings ass backwards when bureaucrats or the military get involved.

  • mchannon 16 hours ago

    It's not sulfur so much as sulfate.

    It doesn't always come from mining. A huge problem with acid rock drainage (ARD) showed up when they built a freeway in Pennsylvania by merely exposing the rock.

    The concept of making batteries out of drainage because both contain sulfur is like making socks out of cow manure because both contain carbon. There's so much of the latter that you could never use it all, but also the ingredient is dirt cheap in pure form.

    I have a side project that could convert ARD into industrial strength sulfuric acid, which is unbelievably difficult to buy and transport, despite it being the most common industrial chemical in the world after water.

    • mapt 14 hours ago

      Acid rock drainage is currently devastating Arctic streams with the melting of pockets of permafrost, which are in effect strip mines.

      https://youtu.be/Lxfpgqn6NOo?feature=shared

      One of the larger sinks for waste sulfur might be stratospheric injection for geoengineering, which is looking increasingly likely.

    • pfdietz 15 hours ago

      It's sulfides like pyrite that, when exposed to air, are oxidized by bacteria to sulfate.

      There's an enormous belt of pyrite in Spain that has caused a river, the Rio Tinto, to be one of the most acid rivers on the planet.

      https://en.wikipedia.org/wiki/Rio_Tinto_(river)

      • mapt 14 hours ago

        I'm not sure the belt of pyrite is best labelled as the cause here.

        It might have something to do with the inferred activities of Rio Tinto, a transnational corporation that is one of the largest mining firms in the world.

        • duskwuff 7 hours ago

          The river was polluted millennia before the Rio Tinto company came into existence. There's been mining operations along the Rio Tinto since ca. 3000 BC.

      • cyanydeez 14 hours ago

        Yes, and it's not just "random" sulfur, it's integral to the geologic complexes that miners look for to get the minerals they want.

        Think of it like the husk of a corn cob, or the cob of your corn. It's a byproduct of the very things we're looking for in mining.

        The only other activity that could get hose minerals is indistinguishable from magic.

  • pfdietz 15 hours ago

    Once we stop using fossil fuels, maybe sulfur in mine tailings will become a valuable resource. Today, sulfur comes from desulfurization of fossil fuels.

  • cyanydeez 14 hours ago

    so long living batteries are a _good thing_.

    Almost everything humans do requires an extensive life cycle analysis.

    but you know, lets just cut everything and pretend that'll improve our assessments of reality.

mrabcx 16 hours ago

"lithium-ion batteries .. degrade after just 1,000 cycles" If you charge your car battery twice a week and complete a full cycle then we are still talking about like 9 years to reach 1000 cycles. If you charge your phone every day, and do a full cycle, then we are close to 2.7 years. But you will probably not do a full cycle. So, I guess lithium-ion batteries are not really that bad.

  • hackingonempty 16 hours ago

    Don't forget calendar life. Lithium batteries degrade over time even if you do not cycle them. The life of the commonly used chemistries is only around 3 years.

    • r00fus 16 hours ago

      Explain my 7.5 year old EV with 95% battery health and 65k miles driven?

      Your 2nd sentence has issues with reality.

      • DylanDmitri 15 hours ago

        Some EVs start with capacity “gated off” to limit the depth of early cycles and provide a more graceful degradation.

        • r00fus 15 hours ago

          But a lifetime of 3y doesn't jive with why my 7 year old vehicle is mostly fully functional. Even with 10% over-provisioning (amazingly expensive 7y ago), that's only a 15% reduction in 7 years.

          The statement "The life of the commonly used chemistries is only around 3 years" is completely misleading and probably inaccurate.

          • freedomben 14 hours ago

            I don't know about the 3 years number, but generally speaking battery lives are estimates/averages based on statistics. If you have a battery that was well cared for it will outperform the average. Also sometimes it's just dumb luck. One aberration isn't nearly enough data to throw out the entire premise

      • saidinesh5 14 hours ago

        It depends on your usage too, along with the exact chemistry and form factor of the lithium battery.

        A lot of people report lithium batteries swelling up in their phones/tablets around 3-4 years of usage.

        • mapt 14 hours ago

          Phone batteries are lithium polymer pouch cells, the least durable type commonly used. Car cells with lithium ion NMC cylindrical cells are much better, and LIFEPO4 in turn is several times more durable than that.

          You would be wise to insist on an EV with LIFEPO4 batteries in the sense that calendar lifetimes are more likely to be on par with traditional engines.

      • kccqzy 13 hours ago

        The explanation is simple. OP said commonly used chemistries. That would be something like LCO. Your EV battery is probably NMC.

    • api 16 hours ago

      Degrade to what extent? I have a 12 year old Nissan Leaf that's lost maybe 25% of its range. Still absolutely usable as a neighborhood car.

      • neogodless 15 hours ago

        A 2013 Nissan Leaf should get 60-75 miles of range (depending on how much of thebattery you use, as well as climate, and other driving conditions). If it got ~80 miles new, it would still get 60 miles now. That might be enough for someone to make a short commute, though unless they have relatively fast charging at home, a 20+ mile commute 5 days a week might be tough to pull off. But most errands would fall well within the existing / remaining range.

        • chgs 2 hours ago

          50 mile round trip at 3 miles per kWh would be under 20kWh, or 1.6kW for 12 hours, about the same as a plug in heater on max, easily doable in a normal socket let alone a dedicated charge circuit.

      • zardo 14 hours ago

        I think most testing uses 80% capacity as the cutoff point. Largely because that's when the loss in capacity really slows down.

      • fredrikholm 15 hours ago

        > neighborhood car

        Not familiar with that term, what does it mean? Shared ride? A car for walking distances?

        • BobaFloutist 15 hours ago

          I think they mean "city car" as opposed to "road trip car" or "rural car."

        • Cupprum 13 hours ago

          Going to work, groceries and so on, the regular stuff.

          If the city was walkable, you would not need such a thing as neighborhood car, you could just use a bike, but apparently as a society at many places we have decided that the cars are the best mode of transportation ever.

      • nuancebydefault 15 hours ago

        If it has moved like 250K km then it is impressive.

  • magicalhippo 12 hours ago

    There's also some research[1] suggesting that dynamic cycling extends lithium-ion battery life, compared to the fixed charge/discharge cycles typically done in a lab setting.

    In this study, we systematically compared dynamic discharge profiles representative of electric vehicle driving to the well-accepted constant current profiles. Surprisingly, we found that dynamic discharge enhances lifetime substantially compared with constant current discharge.

    Specifically, for the same average current and voltage window, varying the dynamic discharge profile led to an increase of up to 38% in equivalent full cycles at end of life.

    [1]: https://www.nature.com/articles/s41560-024-01675-8

  • tecleandor 15 hours ago

    But it could be very interesting for commercial or industrial use: commercial vehicles that are constantly driven and charged, power reserve batteries, tools...

    And I guess that you could make devices with smaller batteries and fast charge, with less fear of wearing them early.

  • flowerthoughts 14 hours ago

    Note that LiFePO/LFP batteries used in cars and large installations are rated for 5,000+ cycles. They really are on another level compared to Li-Co phone batteries that top out at 1,000.

  • WaltYoder 15 hours ago

    For grid-level solar energy, we will need batteries that cycle at least 200 times per year. A system that requires replacing batteries every 5 years can't really be described as "renewable energy".

    • gpm 15 hours ago

      As long as "replace" includes "take the old batteries and turn them into raw materials for making new batteries" it definitely can.

      Typical issues with old batteries are things like dendrite growth. There's nothing wrong with the materials that went into making the battery, they've just reshaped themselves into an unfortunate spiky structure.

  • nomel 13 hours ago

    Most EV map displayed 0% to 100% to something like physical 5% to 95%, or even more extreme, to help.

gamblor956 16 hours ago

This is big news....if it can be refined into a scalable process enabling commercial production.

LI-S batteries have significantly more capacity than commercial Li-[x] batteries of the same weight, but the big weakness until now has been that they have terrible durability.

  • ASalazarMX 16 hours ago

    I'm kinda curios to know if they smell bad because of the sulfur. LiPo smells sweet, like bubblegum, when its electrolyte leaks. Would a Li-S electrolyte leak smell nice like fireworks, or weird like onion/garlic?

antisthenes 17 hours ago

When to comes to batteries, you have to look at multiple factors.

Focusing on just 1, e.g. cycles doesn't give you the whole picture.

1. What is the capacity per $?

2. What is the capacity per kg?

3. What is the capacity per unit of volume?

4. Ease of disposal and recycling

5. Charge and discharge rates.

6. Safety.

7. Viable to produce commercially en masse?

There are just off the top of my head, and not necessarily in that order. The priority will vary depending on your use case.

  • adrian_b 15 hours ago

    There is no doubt about lithium-sulfur batteries being excellent and better than existing lithium-based batteries for conditions 1, 2, 4 and 7.

    Depending on their structure, there may be problems to be solved about their safety and the resistance to corrosion of their components, which may limit the lifetime to lower values than expected from the number of cycles supported by the electrodes.

    Here the sulfur is contained in some kind of borophosphate glass, which should not be easily flammable, so safety or corrosion problems are unlikely.

    An essential component of this new battery is iodine, which has an active redox role, together with lithium and sulfur, iodine being an intermediary in the passing of electrons between lithium and sulfur. Iodine is a rather rare element. Fortunately its extraction from sea water is very cheap, but nonetheless the total amount of available iodine is quite limited, so hopefully the battery needs much less iodine than lithium and sulfur.

    • gpm 15 hours ago

      > Fortunately its extraction from sea water is very cheap, but nonetheless the total amount of available iodine is quite limited,

      Huh? I don't know anything about this, but sea water is very plentiful so if that's where we get it how can the amount available be limited?

  • cman1444 17 hours ago

    To add a few other factors:

    1. Performance in hot/cold environment

    2. Safety can be broken down to chemical toxicity, and thermal stability (likelihood to catch on fire)

    3. Ability to hold a full charge for extended periods of time (self discharge rate)

  • cogman10 16 hours ago

    One of the drawbacks to li-s is that it had terrible cycle life. This is interesting/exciting because they've found a technique to overcome a major disadvantage to a chemistry that ticks a lot of the other checkboxs you've listed.

    The question now is manufacturing, is this something you can use at scale to make batteries.

  • gpm 17 hours ago

    This is research. You should be focusing on "what's new, and is it interesting" not "is the thing they made a good product".

    That said, Li-S typically looks good with respect to potential cost if mass produced (cheap materials), and density metrics. The papers abstract has absurdly good things to say about charge rates. All-solid batteries are typically going to be very safe. So at a glance this research is at least in a very commercializable direction.

    • ahartmetz 17 hours ago

      >All-solid batteries are typically going to be very safe

      Sulfur melts at 115 °C though, so when it overheats, it's not solid anymore. But then, it's apparently not just sulfur, but sulfur embedded in some other stuff, so who knows.

      • adrian_b 15 hours ago

        Here the sulfur is contained in some kind of borophosphate glass, which should have a significantly higher melting point.

  • rcxdude 10 hours ago

    Last I heard of Li-S batteries about 10 years ago, they were fantastic at energy density and safety, looked like they could be pretty cheap to make, but they only lasted about 10 charge cycles, so this is pretty exciting.

  • oakwhiz 17 hours ago

    Exactly. For example the weight of a battery matters very little if used in a stationary application such as a BESS/UPS. But it's very important for transportation e.g. traction power

    • Gibbon1 14 hours ago

      One shouldn't discount the cost of just mass. Feels to me eventually products costs are based on manufacturing complexity, material costs, and energy. Material costs themselves are often energy per unit mass.

  • antisthenes 16 hours ago

    Oh, and another reason why high cycle count may not even be relevant - the battery may become technologically obsolete and non-viable to operate long before it reaches anywhere near the projected cycle count.

    So very high cycle counts (e.g. anything above 4000 cycles ~ 10 years of use) should be taken with a very large grain of salt and may be completely irrelevant for practical uses, unless the application calls for multiple daily discharges (if that's the case, why not use a supercapacitor?)

yapyap 17 hours ago

I hope the better batteries, when they genuinely are deemed to be better, are used in phones and stuff instead of using batteries that’ll go bad in a few years on purpose to drive up sales of new phones.

Even people who can deal with the slower speeds after a few years of owning a phone get driven crazy by having to charge it often, I’d say it’s a big driver if not the biggest to buy a new phone.

  • hackingonempty 16 hours ago

    We already have longer lasting chemistries, lithium iron phosphate. They are also an order of magnitude less likely to go into thermal runaway. However, they are seldom used probably because they are somewhat less energy dense and consumers prioritize size and runtime over battery life and safety. I don't think it is a ploy to drive up sales.

    • chgs 2 hours ago

      Consumers prefer larger tablets to phones, hence Apple abandoning the already large “mini” line after the iphone13

  • master-lincoln 16 hours ago

    You could also just exchange the battery instead of getting a new phone. Of course producers made that more difficult over the years. By 2027 mobile phones sold in the EU are mandated to have a replaceable battery.

AtlasBarfed 17 hours ago

In theory, a Li-S chemistry should be able to outperform Lithium Ion NCM chemistries by a factor of two or three.

Operating temperature range and cycle endurance were some primary barriers, and this seems promising, but ...

"The researchers suggest more work is required to improve the energy density and perhaps to find other materials to use for the mix to ensure a low-weight battery."

ok, nevermind.

  • renox 2 hours ago

    If it's written like this it must be quite low..

    Note though that 'grid batteries' are a very important part for solar transition and they have very different requirement for weight and energy density than electric cars..